Γεωχημική ανάλυση του λιγνίτη της Αχλάδας, Φλώρινα. Κατανομή κύριων στοιχείων και ιχνοστοιχείων, εμπλουτισμός και κινητικότητα αυτών = Geochemical analysis of lignite of Achlada, Florina. Distribution of major and trace elements, enrichment and mobility.
Περίληψη
The main sources of energy in Greece are the lignite deposits, located in the Ptolemais – Kozani – Florina Basin, Western Macedonia, and in Megalopolis, Arcadia Prefecture. The present study investigates the lignite deposit located in Achlada, Florina. The study area is located in the Pelagonian zone of the Inner Hellenides. Data from 40 boreholes, including moisture (%), ash (%), and calorific value (cal/gr) are examined, as well as thirteen lignite samples for the major and trace element concentrations. The same samples were ashed at 750 °C and the major and trace element concentrations were determined in the ashed samples. Chemical analyses were done by ICP-MS for major elements Fe (%), Al (%), for trace elements Li, Be, Sc, V, Cr, Mn, Co, Ni, Cu, Zn, Ga, As, Se, Rb, Sr, Y, Ag, Cd, Cs, Ba, Pb, Bi, Th, U (ppm), and for rare-earth elements (REE) La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu (ppm). The lignite samples were obtained from different wells and depths, to cover the entire study area. By comparing the concentrations between the lignite and ash samples, we conclude the mobility of the elements, the enrichment of the samples, their association with the mineralogy and petrology of the area, and the possible organic relationship with lignite.
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