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Γεωχημική μελέτη λιγνιτών και ενδιάμεσων στείρων ενστρώσεων των κοιτασμάτων Πτολεμαΐδας - Αμυνταίου = Geochemical study of lignite and intermediate sterile layers of deposits in Ptolemais – Amyntaio basin.
Περίληψη
From the mines of the Ptolemaida-Amyntaio basin, a total of 77 samples of lignite and intermediate sterile layers were collected, which were analyzed by XRF and ICP-MS methods to determine their concentrations in major and trace elements. It was also considered appropriate to calculate the pollution index of each trace element in comparison to the global average of coals [World Coals] in the case of lignite samples and in comparison to the average composition of the earth's crust in the case of clay or marl samples. The interpretation of the results showed that the elements Au, Ir, Mo, Se, Ta, W, Tb, Ag, Cd, Bi, Be present concentrations below the detection limit. The elements As, Br, Cs, Hf, Sb, Sc, Sc, Th, U, Sm, Eu, Yb, Lu and Sn show average concentration values <10 ppm, while the elements Co, Cr, Rb, La, Ce, Nd, Cu, Pb, Zn, Ni, Ba, Sr, Y, Zr and V show high concentration values >10 ppm. Elements As, Cr, Sb, U, Ni, and Sn demonstrate significant pollution index, compared to the average concentrations of the earth’s crust or world coals, for a marl-limestone or lignite sample, respectively. As for the major elements, the samples have a low content of total sulfur, MgO and MnO, while the CaO concentrations in the marl samples are high.
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